期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 4, 页码 1158-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja7106349
关键词
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The evolution of a single chiral solid state is reported for an amino acid derivative starting from a nearly racemic mixture of solid left- and right-handed crystals. Attrition-enhanced dissolution and recrystallization processes based on solubility considerations of the Gibbs-Thomson rule, coupled with solution-phase racemization, drive this near-equilibrium system inexorably to single chirality in the solid phase.
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