期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 22, 页码 6930-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja801395y
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资金
- NCI NIH HHS [CA 68685] Funding Source: Medline
- National Research Foundation of Korea [과06A1503, R16-1997-011-01001-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
On the basis of two-photon absorption and time-resolved spectroscopic measurements, as supported by theoretical calculations of quantitative aromaticity, a relationship between the nonlinear optical properties and aromaticity index has been established or a series of four fully conjugate pentapyrrolic expanded porphyrins, namely pentaphyrin (1.1.1.1.1) sapphyrin (1.1.1.1.0), isosmaragdyrin (1.1.1.0.0), and orangarin (1.0.1.0.0), all of which proved amenable to study in dichloromethane.
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