期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 38, 页码 12628-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja805530z
关键词
-
资金
- National Science Foundation [CHE-0615274]
- Department of Education
1-Adamantyl- and mesitylazide react with [(dtbpe)Ni](2)(eta(2)-mu-C6H6) to give the eta(2) organic azide adducts (dtbpe)Ni(eta(2)-N3R) (R = Ad, 3a; Mes, 3b) that have been isolated in good yields and crystallographically characterized. These azide adducts are intermediates in the formation of the corresponding terminal imido complexes (dtbpe)Ni=NR (R = Ad. 4a; Mes, 4b), undergoing intramolecular loss of dinitrogen upon mild thermolysis.
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