期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 36, 页码 12064-12072出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja803049g
关键词
-
资金
- NE MAGMA-NET [NMP3-CT2005-515767]
- DGI [CTQ2006-06333/BQU]
- MIUR [PRIN2006031511]
- Instituto de Salud Carlos III
Fc-PTM is a valence tautomeric radical, where the ferrocene (Fc) group, a good electron donor, is linked by an ethylenic spacer to a perchlorotriphenylmethyl radical (PTM center dot), a good electron acceptor. In solution this compound exists mainly in the neutral Fc-PTM center dot form which can be photoexcited through an intramolecular electron transfer to the zwitterionic Fc(+center dot)-PTM- form. By contrast, in crystals of Fc-PTM at room temperature both the neutral and the zwitterionic forms coexist, pointing to a true bistability phenomenon. We rationalize these findings accounting for the role of intermolecular electrostatic interactions in Fc-PTM crystals. In fact the energy of the zwitterionic Fc(+center dot)-PTM- form is lowered in the crystal by attractive electrostatic intermolecular interactions and the cooperative nature of these interactions explains the observed coexistence of neutral Fc-PTM center dot and zwitterionic Fc(+center dot)-PTM- species. The temperature evolution of Mossbauer spectra of Fc-PTM is quantitatively reproduced adopting a bottom-up modeling strategy that combines a molecular model, derived from optical spectra of Fc-PTM in solution, with a model for intermolecular electrostatic interactions, supported by quantum-chemical calculations. Fc-PTM then offers the first experimental demonstration of bistability induced by electrostatic interactions in crystals of valence tautomeric donor-acceptor molecules.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据