期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 49, 页码 16462-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja8059649
关键词
-
Water oxidation is a key reaction in natural photosynthesis and in many schemes for artificial photosynthesis. Although metal complexes capable of oxidizing water based on Ru, Mn, and Ir are known, a significant question is whether or not dimeric or higher order structures are required for water oxidation. We report here single-site catalytic water oxidation by the monomeric complexes [Ru(tpy)(bpm)(OH2)](2+) and [Ru(tpy)(bpz)(OH2)](2+) (tpy is 2,2':6',2 ''-terpyridine; bpm is 2,2'-bipyrimidine; bpz is 2,2'-bipyrazine) by a well-defined mechanism involving Ru-v square O.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据