期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 34, 页码 11276-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja804277x
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资金
- MEXT
- JSPS
Cobalt-catalyzed reactions of haloalkanes with dimethylphenylsilylmethylmagnesium chloride result in highly regioselective dehydrohalogenation. The reaction does not follow the conventional E2 elimination mechanism but includes beta-hydride elimination from the corresponding alkylcobalt intermediate. The interesting reaction mechanism of the cobalt-catalyzed dehydrohalogenation offered unique transformations that are otherwise difficult to attain.
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