4.8 Article

Conversion of anisotropically phase-segregated Pd/γ-Fe2O3 nanoparticles into exchange-coupled fct-FePd/α-Fe nanocomposite magnets

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 13, 页码 4210-+

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AMER CHEMICAL SOC
DOI: 10.1021/ja077921v

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Exchange-coupled fct-FePd/alpha-Fe nanocomposite magnets were fabricated by converting anisotropically phase-segregated Pd/gamma-Fe2O3 nanoparticles via the interfacial atom diffusion. The magnetically hard fct-FePd phases formed by the interdiffusion between alpha-Fe and fcc-Pd phases nearly preserve their sizes at the nanometer scale because they are surrounded by the alpha-Fe matrix. The VSM measurements reveal that the exchange coupling between the soft and hard phases has been realized.

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