期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 50, 页码 16870-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja8074242
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资金
- American Cancer Society [RSG-06-117-01]
- Arnold and Mabel Beckman Foundation
- Boehringer Ingelheim
- Eli Lilly Co.,
- National Institutes of Health-NIGMS [GM80266]
A stereoselective method for the conversion of allylic alcohols to (Z)-trisubstituted alkenes is presented. Overall, the reaction sequence described is stereochemically complementary to related Claisen rearrangement reactions processes that typically deliver the stereoisomeric trisubstituted alkene containing products.
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