期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 43, 页码 14088-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja806311e
关键词
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资金
- Kurata Memorial Hitachi Science and Technology Foundation
- Nagoya University
- MEXT, Japan
The cooperative asymmetric catalysis of chiral tetraaminophosphonium carboxylate (P,S)-1-OCOR has been established, and its synthetic utility has been successfully demonstrated by application to the highly enantioselective direct Mannich-type reaction of azlactones with N-sulfonyl imines. The present study stimulates the cultivation of the potential of the chiral quaternary onium salt catalysis by the structural modification of organic anion.
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