期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 50, 页码 16854-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja807676v
关键词
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资金
- Takeda Science Foundation
- Naito Foundation
- Nagase Science and Technology Foundation
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [12045232]
- Grants-in-Aid for Scientific Research [12045232] Funding Source: KAKEN
The efficient total synthesis of (-)-serotobenine (1) has been achieved by constructing an optically active dihydrobenzofuran ring via a rhodium carbenoid mediated intramolecular C-H insertion reaction, which was developed by our group. Then the possibility of racemization of 1 was investigated using optically active synthetic 1.
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