期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 34, 页码 11248-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja803344v
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资金
- National Institutes of Health
Rhodium-catalyzed C-H insertion of hydroxylamine-derived sufamate esters makes possible the synthesis of unique oxathiadiazinane heterocycles, which upon mild reduction furnish differentially substituted 1,2-diamine products. This highly chemo- and diastereoselective transformation underscores the power of catalytic C-H functionalization as a general approach to C-N bond construction.
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