期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 130, 期 49, 页码 16492-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja807501a
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资金
- Singapore Ministry of Education Academic [T206B1221, T207BI22ORS]
A highly enantioselective carbonyl-ene reaction catalyzed by In(III)-pybox is described. Both 1, 1-disubstituted alkenes and 1,1,2-trisubstituted alkenes proceeded smoothly to give the ene products in high yields up to 97% and with excellent diastereoselectivity and enantioselectivities up to > 99:1 and 99%, respectively.
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