期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 98, 期 3, 页码 811-818出版社
WILEY-BLACKWELL
DOI: 10.1111/jace.13363
关键词
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资金
- National Natural Science Foundation of China [51472069, U1432113, 51332002]
- opening fund of State Key Laboratory of New Ceramic and Fine Processing at Tsinghua University
New lead-free perovskite solid solution ceramics of (1-x)(Bi1/2Na1/2)TiO3-xBa(Ni1/2Nb1/2)O-3[(1-x)BNT-xBNN,x=0.02-0.06) were prepared and their dielectric, ferroelectric, piezoelectric, and electromechanical properties were investigated as a function of the BNN content. The X-ray diffraction results indicated that the addition of BNN has induced a morphotropic phase transformation from rhombohedral to pseudocubic symmetry approximately at x=0.045, accompanying an evolution of dielectric relaxor behavior as characterized by enhanced dielectric diffuseness and frequency dispersion. In the proximity of the ferroelectric rhombohedral and pseudocubic phase coexistence zone, the x=0.045 ceramics exhibited optimal piezoelectric and electromechanical coupling properties of d(33)similar to 121pC/N and k(p)similar to 0.27 owing to decreased energy barriers for polarization switching. However, further addition of BNN could cause a decrease in freezing temperatures of polar nanoregions till the coexistence of nonergodic and ergodic relaxor phases occurred near room temperature, especially for the x=0.05 sample which has negligible negative strains and thus show the maximum electrostrain of 0.3% under an external electric field of 7kV/mm, but almost vanished piezoelectric properties. This was attributed to the fact that the induced long-range ferroelectric order could reversibly switch back to its original ergodic state upon removal of external electric fields.
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