期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 98, 期 2, 页码 469-475出版社
WILEY-BLACKWELL
DOI: 10.1111/jace.13287
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) [25889049]
- Grants-in-Aid for Scientific Research [25889049] Funding Source: KAKEN
0.6BiFeO(3)-0.4(Bi0.5K0.5)TiO3 (0.6BF-0.4BKT) ceramic samples with 0.0-4.0mol% CuO were prepared by the solid-state reaction. The CuO addition aided the densification of the samples and slightly increased the lattice constant. The relaxor-like defuse dielectric peak of 0.6BF-0.4BKT became sharper with increasing the CuO content. Polarization-electric field curve of the undoped 0.6BF-0.4BKT was a pinched loop in the as-sintered state, while that was a square hysteresis with a large remanent polarization of 48C/cm(2) after the thermal quenching, demonstrating a strong domain wall pinning due to defect dipoles. We found that the CuO addition up to 2.0mol% facilitates the polarization switching in the as-sintered samples to increase the remanent polarization and the piezoelectric d(33) coefficient. The results of the structural and electrical investigations suggested that the copper ion acts as a donor in 0.6BF-0.4BKT by compensating the potassium vacancy created by the evaporation of K2O during the calcination and sintering processes.
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