期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 96, 期 12, 页码 3939-3948出版社
WILEY
DOI: 10.1111/jace.12620
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-
资金
- Mexican National Council of Science and Technology (Conacyt) [53563]
This research examines the chemical activation of blast-furnace slag pastes with alkaline solutions by means of various characterization techniques. Pastes were activated using sodium silicate solutions with modulus (Ms) of 0, 1, 1.5, 2, and Na2O at 5%, 10%, and 15%. Compressive strengths of up to 108MPa were achieved for Ms=1-1.5 after 720d of curing at 20 degrees C. The addition of Na2O>10% resulted in the formation of hydrotalcite and carbonated pastes with low compressive strength. X-ray diffraction, microanalysis of outer products (OP), and nuclear magnetic resonance (NMR) results showed that the main reaction products in the activated cements with Ms=1 and 5%Na2O had an average ratio Ca/Si=0.71-0.9 and consisted of a mixture of two kinds of C-S-H; one similar to a 9 angstrom tobermorite-type calcium silicate hydrate (Ca5Si6O16(OH)(2) and other amorphous related to a cross-linked structure of C-N-(A)-S-H gel. Both were intermixed with hydrotalcite and cross-linked structures of silica gel.
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