4.7 Article

Meso/Macroporous Ceria with Enhanced Surface oxygen Activity via Plant-Leaf Mineralization

期刊

JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 93, 期 1, 页码 40-43

出版社

WILEY
DOI: 10.1111/j.1551-2916.2009.03361.x

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资金

  1. National Natural Science Foundation of China [50972090]
  2. Dawn Program of Shanghai Education Commission [08SG15]
  3. Major Fundamental Research Project of Shanghai Science Committee [07DJ14001]
  4. National Basic Research Program of China [2006CB601200]
  5. Sino-Finland International Program of Shanghai [09520703400]
  6. Sino-France International Program of MOST, China [2009DFA52410]
  7. Foundation of Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education). Shandong University

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Biomorphic cerias were produced through mineralizing plant-leaf templates (camphor and common oleander) with a cerium nitrate precursor. They were mesoporous while inheriting the species-de pendent macrofeatures of plant-leaf templates, like macropores, channels, and microfibrous clusters, to have a meso/macroporous hierarchy. Surface oxygen activity was enhanced for the biomorphic cerias, as was revealed by temperature-programmed reduction measurements, suggesting their potentials in mid-temperature (300 degrees-600 degrees C) applications of oxygen storage, catalysis, gas sensing, etc.

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