4.7 Article

High-Energy Density Capacitors Utilizing 0.7 BaTiO3-0.3 BiScO3 Ceramics

期刊

JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 92, 期 8, 页码 1719-1724

出版社

WILEY
DOI: 10.1111/j.1551-2916.2009.03104.x

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资金

  1. National Science Foundation [0120812]
  2. Penn State University Materials Research Institute NanoFabrication Network
  3. National Science Foundation Cooperative [0335765]
  4. National Nanotechnology Infrastructure Network
  5. Directorate For Engineering
  6. Div Of Electrical, Commun & Cyber Sys [0335765] Funding Source: National Science Foundation
  7. Directorate For Engineering
  8. Div Of Industrial Innovation & Partnersh [0120812] Funding Source: National Science Foundation

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A high, temperature-stable dielectric constant (similar to 1000 from 0 degrees to 300 degrees C) coupled with a high electrical resistivity (similar to 10(12) center dot cm at 250 degrees C) make 0.7 BaTiO3-0.3 BiScO3 ceramics an attractive candidate for high-energy density capacitors operating at elevated temperatures. Single dielectric layer capacitors were prepared to confirm the feasibility of BaTiO3-BiScO3 for this application. It was found that an energy density of about 6.1 J/cm(3) at a field of 73 kV/mm could be achieved at room temperature, which is superior to typical commercial X7R capacitors. Moreover, the high-energy density values were retained to 300 degrees C. This suggests that BaTiO3-BiScO3 ceramics have some advantages compared with conventional capacitor materials for high-temperature energy storage, and with further improvements in microstructure and composition, could provide realistic solutions for power electronic capacitors.

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