期刊
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
卷 92, 期 10, 页码 2300-2310出版社
WILEY
DOI: 10.1111/j.1551-2916.2009.03219.x
关键词
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资金
- National Science Foundation [DMR-0746902, OISE-0755170]
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0746902] Funding Source: National Science Foundation
Structural changes such as non-180 degrees domain wall motion and lattice strains in Pb(Zr, Ti)O-3 ceramics are measured during the application of subcoercive cyclic electric fields using time-resolved high-energy X-ray diffraction with a stroboscopic data collection technique. The contributions to the electric-field-induced strains from non-180 degrees domain wall motion and lattice distortions are determined as a function of material composition and type of dopant. For the different compositions studied, the largest strains due to non-180 degrees domain wall motion are measured for La-doped tetragonal ceramics with a composition close to the morphotropic phase boundary. It is further observed that strain contributions from both non-180 degrees domain wall motion and lattice distortions can be nonlinear with respect to the applied electric field. The correlation between the electric-field-induced structural changes and the macroscopic piezoelectric properties is discussed.
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