期刊
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN
卷 69, 期 5, 页码 542-551出版社
SOC SYNTHETIC ORGANIC CHEM JPN
DOI: 10.5059/yukigoseikyokaishi.69.542
关键词
microflow reactor; insoluble polymeric metal catalysts; palladium; tungsten; catalytic membrane of polymeric metal species; Suzuki-Miyaura reaction; allylic arylation; Mizoroki-Heck reaction; instantaneous organic transformation reactions; micro-device
Highly active and reusable solid-phase catalysts were developed with our 'molecular convolution methodology' where a soluble linear polymer having multiple ligand groups was convoluted with transition metals via coordinative or ionic complexation to achieve the one-step preparation of the insoluble polymeric metal composite. These convoluted polymeric-palladium nanoparticles, -phosphotungstate salt, and -palladium complex promoted the organic transformations with high reusability to give the corresponding products quantitatively. Moreover, instantaneous catalytic cross-coupling reactions were achieved in the catalytic membrane-installed microchannel devices having a polymeric palladium complex membrane. The catalytic membrane-installed microchannel devices were installed inside the microchannels via the molecular convolution at the interface between the organic and aqueous phases flowing laminarly. The microflow device-catalyzed Suzuki-Miyaura reaction was performed at 50 degrees C to give the product quantitatively within 5 sec of residence time. They were applied to the allylic arylation at 70 degrees C to afford the corresponding products quantitatvely within 1 sec of residence time.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据