期刊
JOURNAL OF SURFACTANTS AND DETERGENTS
卷 16, 期 4, 页码 559-569出版社
WILEY
DOI: 10.1007/s11743-012-1390-8
关键词
Acid inhibitors; Hydrochloric acid; Polarization curve; Adsorption; Weight loss
资金
- National Natural Science Foundation of China [40806030]
The surface properties of a series of imidazo-line-based dissymmetric bis-quaternary ammonium (DBA) salts with different hydrophobic chain lengths DBA-12, DBA-14 and DBA-16 were determined. The adsorption behaviors of these compounds in 1 M HCl solution and their inhibitive effect on Q235 steel (U12350) were investigated using the weight-loss method, polarization, and electrochemical impedance spectroscopy. Results indicate that the three inhibitors all showed good inhibition performance for Q235 Steel in 1 M HCl solution and were found to be mixed-type inhibitors. The adsorption behavior of the three inhibitors can fit the Langmuir isotherm equation and the values of Delta G(ads)(0) are around or lower than 40 kJ mol(-1), indicating that there is a stronger chemical adsorption.
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