期刊
JOURNAL OF SURFACTANTS AND DETERGENTS
卷 12, 期 3, 页码 185-190出版社
WILEY
DOI: 10.1007/s11743-009-1109-7
关键词
Gemini surfactant; Interfacial tension; Salt; Temperature; Polymer
资金
- CNPC Innovation Foundation [2008D-5006-02-05]
- Key Laboratory Fund of Sichuan [2006ZD047]
- Sichuan Youth Science & Technology Foundation [08ZQ026-001]
- Hi-Tech Research and Development Program of China [2007AA090701]
The effects of the hydrocarbon chains and spacer groups of gemini surfactants, salt, temperature, and polymer on the interfacial tension of crude oil-water mixtures were investigated in this paper. The length of the alkyl chain is a major factor affecting the properties of a gemini surfactant, and the spacer group is also an important factor influencing the surfactant properties. The addition of salt results in a great decrease in the CMC and favors the reduction of interfacial tension, which shows that a gemini surfactant has a good synergism with salt. Variation in temperature will affect the dynamic and equilibrium interfacial tension, and increasing the temperature can shorten the time to reach the equilibrium and decrease the equilibrium interfacial tension in the range of experimental temperatures. With the addition of polyacrylamide (PAM), it takes longer to reach equilibrium, but this has little effect on the value of equilibrium interfacial tension.
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