期刊
JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM
卷 27, 期 8, 页码 1867-1871出版社
SPRINGER
DOI: 10.1007/s10948-014-2521-4
关键词
Bismuth ferrite; Structural characterization; Magnetic properties; Optical properties
资金
- Department of Science and Technology (DST), India [SR/FTP/PS-91/2009]
Non-magnetic Zr4+ ions substituted BiFeO3 nanoparticles (BiFe1-x Zr (x) O (3), x = 0.0, 0.03 and 0.10) were synthesized by sol-gel method. X-ray diffraction and Raman studies indicate the rhombohedral phase for all the samples. The particle size decreases with increasing Zr4+ concentration and varies in the range 20-50 nm. The absorption spectra show the strong absorption of visible light with optical band gap variation 2.27-2.21 eV for pure and Zr-doped BFO nanoparticles. A large saturation magnetization value of 9.33 emu/g is observed for x = 0.03 sample. The reduction in saturation magnetization for x = 0.10 sample is attributed to the dominant role of an increasing number of non-magnetically active Zr4+ ions, and the formation of Fe-O-Zr coordination with increasing Zr4+ ions concentration becomes less magnetic sublattice.
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