期刊
JOURNAL OF STRUCTURAL CHEMISTRY
卷 53, 期 4, 页码 768-775出版社
PLEIADES PUBLISHING INC
DOI: 10.1134/S002247661204021X
关键词
ionic clathrate hydrates; tetrabutyl ammonium propionate; structure; disordering
资金
- RFBR [09-03-00367]
Single crystal X-ray diffraction is used for the first time to study the structure of the ionic clathrate hydrate of tetrabutyl ammonium propionate (C4H9)(4)NC2H5COO center dot 27.0H(2)O with the host framework based on cubic arrangement I. The structural model is characterized by a high degree of disordering in both guest and host subsystems. The structural features indicate a colocation of cations and anions in multicell 4T center dot nD cavities with n = 0-4; the simplest option is a pairwise location of cations and anions in combined five-cell 4T center dot D cavities. The positional ordering of cations leads to the formation of a 2x2x2 supercell (space group , a = 24.312(6)). The resulting model confirms the characteristic features of ionic clathrate hydrates of tetrabutyl and tetraisoamyl ammonium carboxylates. Non-standard refinement techniques are described, which may be of interest for other structures with a high degree of disordering. The proposed structural interpretation can serve as a basis for a further investigation of this class of compounds by other methods.
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