期刊
JOURNAL OF STRUCTURAL CHEMISTRY
卷 50, 期 3, 页码 566-569出版社
SPRINGER
DOI: 10.1007/s10947-009-0086-z
关键词
thallium; praseodymium; hafnium; binary molybdates; kosnarite; crystal structure
资金
- RFBR [04-03-32714a, 08-08-00958a]
Crystals of binary praseodymium and hafnium molybdate of Pr2Hf3(MoO4)(9) composition are grown by solution-melt crystallization under spontaneous nucleation conditions. By the X-ray diffraction data (X8 Apex automated diffractometer, MoK alpha radiation, 2262 F(hkl), R = 0.0170) its composition and crystal structure are determined. Parameters of the trigonal unit cell are: a = b = 9.8001(1) angstrom, c = 58.7095(8) angstrom, V = 4883.15(10) angstrom(3), Z = 6, space group R (3) over barc. The crystal structure is composed of three types of polyhedra: MoO4 tetrahedra, HfO6 octahedra, and nine-vertex PrO9. All three types of polyhedra are bonded among themselves by common oxygen vertices of bridging MoO4 tetrahedra forming an openwork three-dimensional structure.
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