期刊
APPLIED PHYSICS LETTERS
卷 106, 期 20, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.4921485
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资金
- Office Naval Research [N00014-14-1-0109]
- Nanjing University
- China Scholarship Council
Developing dielectric polymers with higher dielectric constant without sacrificing loss and thermal stability is of great importance for next generation of high energy density capacitors. We show here that by replacing the CH2 group in the aromatic polyurea (ArPU) with the polar ether group, thus raising the dipole moment of the molecular unit, poly(arylene ether urea) (PEEU) shows an increased dielectric constant of 4.7, compared with 4.2 of ArPU. Moreover, PEEU maintains the low dielectric loss and is thermally stable up to 250 degrees C. As a result, the polymer delivers 13 J/cm(3) discharged energy density at room temperature and 9 J/cm(3) at 120 degrees C. The high quality films perform well in terms of both breakdown strength (at 700 MV/m at room temperature) and leakage current from room temperature to elevated temperature. At 120 degrees C, the breakdown strength is 600 MV/m and the conductivity is 1.58 x 10(-14) S/cm measured under 100 MV/m. (C) 2015 AIP Publishing LLC.
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