期刊
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
卷 19, 期 3, 页码 861-870出版社
SPRINGER
DOI: 10.1007/s10008-014-2692-8
关键词
Reduced graphene oxide; Electrochemical sensor; Hydroquinone; Catechol
资金
- National Natural Science Foundation of China [21105002]
- Innovative project for Young Scholar
- Henan province [14HASTIT012, 2013GGJS-147]
- Henan Key Technologies RD Program [122102310516, 12B150002]
- Innovative Foundation for the College students of China [201310479012]
We compared the electrochemical performance of various reduced graphene oxides (RGOs), including chemically reduced graphene oxide (CRGO), thermally reduced graphene oxide (TRGO), and electrochemically reduced graphene oxide (ERGO) under different reduction potentials, using aromatic species of hydroquinone and catechol as analytes. Strong adsorption of analytes on RGOs surface is found due to pi-pi interaction between RGOs and aromatic species. Analytical parameters of electron transfer rate, detection sensitivity, and linear response range were considered. CRGO showed the fastest heterogeneous electron transfer rate and the most wide linear range but among the poorest detection sensitivity. The different restoration extent of graphitic network, such as ERGO prepared under different reduction potentials, will also affect the sensing performance. These results will enhance our understanding of the applicability of RGOs in biosensing.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据