期刊
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
卷 18, 期 2, 页码 445-452出版社
SPRINGER
DOI: 10.1007/s10008-013-2245-6
关键词
Solid oxide fuel cell; Metallic interconnect; High-temperature oxidation; Protective coating; Spinel oxide
资金
- Materials Technology Development Program [10037312]
- Ministry of Knowledge Economy (MKE, Korea)
- Korea Evaluation Institute of Industrial Technology (KEIT) [10037312] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
(Mn,Cu)(3)O-4-based conductive oxides are examined as protective coatings to improve the surface stability of metallic interconnects for solid oxide fuel cells at high temperatures. Nano-sized Mn3 -aEuro parts per thousand x Cu (x) O-4 materials with various Cu contents (x = 1.0-1.5) are synthesized and a composition-structure-property relationship is experimentally determined. The Cu content (x) has a significant influence on phase stability as well as sintering, electrical, and thermal expansion characteristics. Thin and dense Mn3 -aEuro parts per thousand x Cu (x) O-4 coatings are fabricated on the interconnects (Crofer 22 APU) by a slurry coating process and subsequent heat treatment. The coated interconnects exhibit area-specific resistances as low as 7.1-15.0 m Omega cm(2) at 800 A degrees C. The electrochemical cell shows no performance degradation in the presence of the Mn3 -aEuro parts per thousand x Cu (x) O-4-coated interconnect. The results indicate that the Mn3 -aEuro parts per thousand x Cu (x) O-4 coatings act as an effective barrier to high-temperature oxidation of the metallic interconnects.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据