期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 211, 期 -, 页码 176-183出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2013.12.027
关键词
T-shaped BiVO4; Hydrothermal method; Methylene Blue; Photocatalytic; Visible light
资金
- Basic Scientific and Technological Frontier Project of Henan Province, PR China [102300410193, 132330410138, 122300410293]
- Innovation Scientists and Technicians Troop Construction Projects of Henan Province
- Plan for Scientific Innovation Talent of Henan Province [134200510014]
A novel T-shaped BiVO4 microcrystal photocatalyst was successfully synthesized by the hydrothermal method with the aid of a structure-directing surfactant SOBS in the present study. Having received well characterization with the aid of various techniques and the results showed that the SOBS greatly changed the microstructure of BiVO4, which had a unique T shape and belonged to the monoclinic family. The fast exchange dynamics between the surfactants bound to the Bi3+ seed surface and the free VO3- in the solution significantly increase the rate of heterogeneous nucleation. In addition, the photocatalytic activity of the prepared T-shaped BiVO4 was evaluated by the degradation of Methylene Blue solution under visible light irradiation, 17% and 47% higher decolorization rates than the commercial P25 and BiVO4 synthesized without SOBS, respectively. Meanwhile, it has been found that the degradation kinetics of MB fitted the pseudo-first-order kinetics and the T-shaped BiVO4 also displayed high photocatalytic performance for metronidazole degradation. (C) 2014 Elsevier Inc. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据