Auxiliary aromatic-acid effect on the structures of a series of Zn-II coordination polymers: Syntheses, crystal structures, and photoluminescence properties

Five novel Zn-II-(pyridyl)imidazole derivative coordination polymers, [Zn(L)(2)] (1), [Zn-2(mu(3)-OH)L(m-BDC)] (2), [Zn-2(mu(3)-OH)L(p-BDC)]center dot H2O (3), [Zn2L(BTC)(H2O)]center dot 2.5H(2)O (4) and [Zn-3.5(mu(3)-OH)L-2(BTEC)(H2O)]. H2O (5) (L=4-((2-(pyridine-2-y1)-1H-imidazol-1-yl)methyl)benzoic acid, p-H2BDC=1,4-benzenedicarboxylic acid, m-H2BDC=1,3-benzenedicarboxylic acid, H3BTC=1,3,5-benzenetricarboxylic acid, H4BTEC=1,2,4,5-benzenetetracarboxylic acid), were successfully synthesized under hydrothermal conditions through varying auxiliary aromatic-acid ligands and structurally characterized by X-ray crystallography. Compound 1 exhibits a 1D chain linked via double L bridges. Compound 2 features a well-known pcu topology with bent dicarboxylate ligand (m-H2BDC) as an auxiliary ligand, while 3 displays a bat network with linear dicarboxylate ligand (p-H2BDC) as an auxiliary ligand. The structure of compound 4 is a novel 3D (3,5)-connected network with (4.6(2))(4.6(4).8(2).10.12(2)) topology. It is interesting that compound 5 shows an intricate (3,4,8)-connected framework with (4.6(2)) (4(2).6(3).8)(4(2).6(4))(4(2).6(18).7.8(6).10) topology. In addition, their infrared spectra (IR), X-ray powder diffraction (XPRD) and photoluminescent properties were also investigated in detail. (C) 2010 Elsevier Inc. All rights reserved.