期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 182, 期 4, 页码 725-729出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2008.12.027
关键词
Pyrochlore; Yttrium titanate; Heat capacity; Thermal conductivity; Thermodynamics
资金
- NSERC of Canada
- Killam Trusts
- Canada Foundation for Innovation
- Atlantic Innovation Fund
The thermal conductivity and heat capacity of high-purity single crystals of yttrium titanate, Y2Ti2O7. have been determined over the temperature range 2 K <= T <= 300 K. The experimental heat capacity is in very good agreement with an analysis based on three acoustic modes per unit cell (with the Debye characteristic temperature, theta(D), of ca. 970 K) and an assignment of the remaining 63 optic modes, as well as a correction for C-p-C-v. From the integrated heat capacity data, the enthalpy and entropy relative to absolute zero, are, respectively, H(T = 298.15 K)-H-0 = 34.69 kJ mol(-1) and S(T = 298.15 K)-S-0 = 211.2J K-1 mol(-1). The thermal conductivity shows a peak at ca. theta(D)/50, characteristic of a highly purified crystal in which the phonon mean free path is about 10 mu m in the defect/boundary low-temperature limit. The room-temperature thermal conductivity Of Y2Ti2O7 is 2.8 W m(-1) K-1, close to the calculated theoretical thermal conductivity, kappa(min), for fully Coupled phonons at high temperatures. (C) 2008 Elsevier Inc. All rights reserved.
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