Synthesis and performance of carbon-coated Li3V2(PO4)(3) cathode materials via an oxalic acid-based sol-gel route using PEG

Li3V2(PO4)(3)/C (LVP/C) composite materials have been successfully synthesized via a sol-gel method with oxalic acid as chelating agent and polyethylene glycol (PEG) as the supplementary carbon source, in which oxalic acid and PEG serve as double carbon sources. The X-ray diffraction patterns indicate that all of the samples are well crystallized. Transmission electron microscopy images reveal that the LVP/C sample prepared with 10 wt% PEG is uniformly coated by carbon layer with an appropriate thickness of 10-16 nm, resulting in a high electrical conductivity and a fast kinetics. The Li+ diffusion coefficient in the LVP/C sample prepared with PEG is 3.482 x 10(-13) cm(2) s(-1), which is larger than that of the LVP/C sample prepared without PEG. In the range of 3.0-4.3 V, the LVP/C-10 electrodes exhibit good rate capability and excellent cyclic performance, which discharge capacities are 131.9 mAh g(-1) at 0.1 C and 105.3 mAh g(-1) at 5 C. The present work provides a valuable route for preparing lithium metal phosphates with double carbon sources to improve the conductivity and hence the electrochemical performance.