4.6 Article

Three-dimensional flower-like nickel oxide supported on graphene sheets as electrode material for supercapacitors

期刊

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
卷 63, 期 1, 页码 146-152

出版社

SPRINGER
DOI: 10.1007/s10971-012-2778-7

关键词

Graphene sheets; NiO; Supercapacitor; Hydrothermal

资金

  1. National Natural Science Foundation of China [50802028]
  2. Hunan Provincial Natural Science Foundation of China [10JJ2036]
  3. Research Foundation of Education Bureau of Hunan Province, China [09A036]
  4. Innovation Platform Open Fund Projects in Higher Educational Institutions of Hunan Province [09K096]

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Dispersed three-dimensional (3D) flower-like nickel oxide on graphene sheets was synthesized by incorporating a facile hydrothermal process with a thermal treatment process. The possible growth mechanism of 3D flower-like NiO is discussed. When used as electrode materials for supercapacitors, the resultant composite exhibits a specific capacitance of 346F/g (1.5A/g), a good rate performance and cycle stability in 2 M KOH. NiO in the composite could provide a specific capacitance as high as 778.7F/g, compared to that of bare NiO of only 220F/g. The functional features of unique 3D flower-like NiO morphology, high conductivity of graphene sheets and its protective effect to the structure of NiO result in an improved electrochemical performance.

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