Opposite effect of Li+ codoping on the upconversion emissions of Er3+-doped TiO2 powders

The Er3+-Li+ codoped TiO2 powders have been prepared by the non-aqueous sol-gel method. The green and red upconversion emissions centered at about 526, 550 and 663 nm were observed by the H-2(11/2), S-4(3/2) -> I-4(15/2) and F-4(9/2) -> I-4(15/2) transitions of Er3+, respectively. Li+ codoping has opposite effect on the upconversion emissions intensities for Er3+-doped TiO2 at sintering temperatures of 1,073 and 1,273 K. At 1,073 K, the Er3+-doped TiO2 phase transition from anatase to rutile was accelerated with increasing Li+ codoping concentration, leading to the increase of crystal field symmetry of Er3+, thus the upconversion emissions intensities decreased. At 1,273 K, Li+ codoping had no effect on the phase structure of Er3+-doped TiO2 and only increased the Er-O bond length, it indicated that the upconversion emissions intensities greatly enhanced because of the decrease of crystal field symmetry of Er3+.