期刊
JOURNAL OF SEPARATION SCIENCE
卷 36, 期 15, 页码 2522-2529出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jssc.201201091
关键词
Liquid chromatography-mass spectrometry; Pesticide residues; QuEChERS
资金
- research project of China Tobacco [2011YN01]
- National Natural Science Foundation of China [21275088]
A quick, easy, cheap, effective, rugged, and safe (QuEChERS) sample pretreatment method coupled with LC-MS was developed for the determination of 11 pesticides in tobacco. Sample pretreatment parameters and instrumental parameters of LC-MS were investigated, and the optimal conditions were selected. Under the optimized conditions, the 11 pesticides were detected simultaneously with a good linear relationship (r(2) = 0.9993-0.9999) and high precisions (less than 5% of the RSD of peak areas). The LODs were in the range of 0.1-5.0 mu g/L. Compared with SPE clean-up, QuEChERS greatly simplified the sample pretreatment with simple solvent extraction system. After QuEChERS pretreatment, no serious matrix effects were observed. Used for the analysis of real samples, metalaxyl was found in cigarette and tobacco samples at 63.47 and 132.27 ng/g, respectively. The recoveries for 11 pesticides were in the range of 70.03-118.69%, and RSDs were less than 10%. The proposed method is simple, low cost, and has good reproducibility.
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