期刊
JOURNAL OF SEPARATION SCIENCE
卷 32, 期 19, 页码 3310-3318出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jssc.200900407
关键词
Cyromazine; Environmental water; Melamine; Molecularly imprinted polymers; Solid-phase extraction
资金
- National Science and Technology [2006BAD311306]
- South China Agricultural University
A method for molecularly imprinted SPE of the melamine from environmental water samples was investigated. Cyromazine-imprinted polymers were synthesized in water-methanol systems for the selective extraction of melamine from aqueous samples, followed by HPLC analysis. Molecular recognition properties and binding capability to melamine were evaluated by adsorption test and Scatchard analysis, which showed the dissociation constant (KD) and the maximum binding quantity (Q(max)) were 0.032 mu mol/L and 4.77 mu mol/g for high affinity binding site, and 0.26 mu mol/L and 19.10 mu mol/g for lower affinity binding site, respectively. Under the optimum extraction protocol, the method can be successfully applied to selectively extract and enrich melamine in environmental water. The linearity was ranged from 0.500 to 100.0 ng/mL (r > 0.999) in tap water, lake water, and seawater analysis. When 50 mL of the water samples loaded, the LODs of the method were ca. 0.1 ng/mL, and the LOQs were ca. 0.5 ng/mL. The mean recoveries of melamine from blank water samples spiked at 0.5, 5.0, and 50 ng/mL were more than 86.3%, with the RSD less than 8.8%.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据