期刊
JOURNAL OF RHEOLOGY
卷 54, 期 5, 页码 1155-1172出版社
JOURNAL RHEOLOGY AMER INST PHYSICS
DOI: 10.1122/1.3478316
关键词
-
类别
资金
- EU
- F.N.R.S
- Communaute Francaise de Belgique
In this manuscript, we extend the tube-based model that we developed for predicting the linear viscoelasticity of entangled polymers [van Ruymbeke et al., J. Non-Newtonian Fluid Mech. 128, 7-22 (2005)] to the prediction of the extensional rheology of monodisperse and bidisperse linear polymers and confront the results to experimental data. This model is based on the concepts of stretch-orientation separability [McLeish and Larson, J. Rheol. 42, 81-110 (1998)] and inter-chain pressure [Marrucci and Ianniruberto, Macromolecules 37, 3934-3942 (2004)]. In order to deal with polydisperse samples, a new mixing law is proposed. As it does not require knowledge of the full linear relaxation spectrum, the proposed model is a powerful predictive tool. Very good agreement is found between theoretical and experimental results. For bidisperse samples, the individual contribution of each component is determined, and it is shown that only few percent of long chains are enough to generate the strong strain hardening observed in the experimental data. Last, we discuss the value of the tube diameter relaxation time. For monodisperse samples, this parameter is found to scale with M-2. However, for bidisperse samples, as it was already observed by Wagner et al. [J. Rheol. 52, 67-86 (2008)], the tube diameter relaxation time of the long component must be rescaled, which is contrary to the inter-chain pressure model and opens several new questions. (c) 2010 The Society of Rheology. [DOI:10.1122/1.3478316]
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据