期刊
ACTA CHIMICA SINICA
卷 73, 期 6, 页码 530-540出版社
SCIENCE PRESS
DOI: 10.6023/A15020096
关键词
microporous; hypercrosslinked polymers; post-crosslinking; self-polycondensation; external crosslinking
资金
- National Natural Science Foundation of China [21474033, 51273074, 51173058]
- Program for New Century Excellent Talents in University [NCET-10-0389]
Hypercrosslinked microporous polymers are currently an important class of porous polymer materials and receiving great interest due to their advantages such as high surface area, moderate synthetic conditions and diverse building blocks. According to the difference between the synthetic methods, hypercrosslinked polymers are mainly prepared by the following three strategies: polymer precursor post-crosslinking, one-step self-polycondensation of multifunctional monomers and external crosslinker knitting rigid aromatic compounds. In this review, we introduce the development of hypercrosslinked polymer in detail as well as investigate various synthetic methods and polymer networks with controlled micro-morphology, the broad practical and potential applications including gas storage, adsorption, separation and heterogeneous catalysis were also discussed. In the end, we talk about the disadvantage of hypercrosslinked polymers and challenges in the future as well as predict the further development on synthesis and application.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据