期刊
JOURNAL OF RARE EARTHS
卷 30, 期 4, 页码 361-366出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1002-0721(12)60059-3
关键词
hydrogen storage alloy; Co-free; Fe-containing; composition optimization; electrochemical characteristics; uniform design; rare earths
资金
- Guangdong-Ministry of Education (GD-MOE) [2008B090500274]
- Chengdu Key Technologies RD Program [10GGYB897GX-023]
In order to reduce the cost of AB(5)-type hydrogen storage alloys, effects of substitution of Ce for La (A side) and Fe, Mn, Al for Ni (B side) on structural and electrochemical properties of (LaCe)(1)(NiFeMnAl)(5) alloys were studied systematically. To make component uniform and operation easy, uniform design (UD) method was introduced into the study of composition optimization of Co-free Fe-containing AB(5)-type alloys for the first time. X-ray diffraction (XRD) results showed that the designed alloys were of single CaCu5-type structure phase. The replacement of Fe had a severe effect on electrochemical capacity, and the substitution of Fe and Al had a synergetic action among the unit cell volume, cycling stability and high rate discharge property. Interestingly, it was found that the hydrogen storage alloys with excessively high plateau pressure showed a tilted line in Nyquist plot instead of the semicircle, and the current decayed rapidly to near zero at the beginning of the step in constant potential step (CPS), indicating that electrochemical impedance spectra (EIS) and CPS cannot accurately measure the electrochemical kinetics process of the hydrogen storage alloys with excessively high plateau pressure.
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