期刊
JOURNAL OF RAMAN SPECTROSCOPY
卷 40, 期 12, 页码 1931-1934出版社
JOHN WILEY & SONS LTD
DOI: 10.1002/jrs.2342
关键词
linear carbon chains; Huckel theory; electron-phonon coupling; Raman spectroscopy; pi-electron confinement
类别
资金
- Italian Ministry of Education
- University and Research [RBNE033KMA, RBNE019NKS]
A theoretical model based on Huckel theory is presented and applied to the infinite linear carbon chain. The effect of Peierls distortion, pi-electron confinement and electron-phonon coupling are interpreted on the basis of measurable parameters such as bond length alternation, electronic gap and Raman wavenumbers. A diagram is presented where the correlation among these quantities is shown on the basis of the model adopted. The effect of pi-electron confinement on experimental data can be directly evaluated, and insights on the physical properties of these materials can be derived. Copyright (C) 2009 John Wiley & Sons, Ltd.
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