期刊
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
卷 293, 期 2, 页码 601-612出版社
SPRINGER
DOI: 10.1007/s10967-012-1703-4
关键词
Plutonium nitrate; Solutions; Activity coefficients; Chemical equilibrium
资金
- U.S. Department of Energy [DE-AC52-06NA25396]
Plutonium nitrate solutions contain a large number of chemical species and they exhibit significant deviations from ideal behavior. Modeling this system is challenging. A model that includes all known chemical species and accounts for nonideal solution behavior could contain several hundred unknown parameters, but insufficient published data exists for evaluating large numbers of parameters. A practical model of plutonium nitrate solutions, therefore, must be a compromise between the number of chemical species included and the number of parameters that can be evaluated from available data. A practical model of acidic plutonium nitrate was developed. The model, which was based on an extended UNIQUAC-Debye-Huckel equation, captures the essential behavior of the system with a minimum number of chemical species. It is capable of representing the vapor-liquid equilibrium data for the nitric acid-water system, the activity of water in the plutonium nitrate-nitric acid-water system, the distribution of plutonium-nitrate complexes in aqueous nitric acid solution, and plutonium adsorption on an anion exchange resin.
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