期刊
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
卷 283, 期 1, 页码 45-50出版社
SPRINGER
DOI: 10.1007/s10967-009-0048-0
关键词
Extraction; Americium; Europium; 1,2-(Diphenylphosphino)ethylene dioxide; Dicarbollylcobaltate; Nitrobenzene
资金
- Czech Ministry of Education, Youth and Sports [MSM 4977751303, MSM 6076137307]
Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of 1,2-(diphenylphosphino)ethylene dioxide (DPPEDO, L) has been investigated. The equilibrium data have been explained assuming that the cations HL+, HL2+; ML23+; ML33+ and ML43+ (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. It has been found that the stability constants of the corresponding complexes EuLn3+ and AmLn3+, where n = 2, 3, 4 and L is DPPEDO, in water saturated nitrobenzene are comparable.
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