期刊
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
卷 277, 期 2, 页码 495-497出版社
SPRINGER
DOI: 10.1007/s10967-007-6993-6
关键词
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From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M(+)(aq)+NaL(+)( nb) double left right arrow ML(+)( nb)+ Na(+)(aq) taking place in the two-phase water - nitrobenzene system (M(+) = Li(+), H(3)O(+), NH(4)(+), Ag(+); L = hexaethyl calix[ 6] arene hexaacetate; aq = aqueous phase, nb = nitrobenzene phase) were determined. Furthermore, the stability constants of the ML+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the cation order H(3)O(+)
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