Temperature-dependent luminescence and temperature-stimulated NIR-to-VIS up-conversion in Nd3+-doped La2O3-Na2O-ZnO-TeO2 glasses

Telluride glasses of the composition xNd(2)O(3)-(7-x)La2O3-3Na(2)O-25ZnO-65TeO(2), where (0 <= x <= 7) were prepared by the melt quench technique. Some physical and optical properties of the glasses were evaluated. The thermal behavior i.e., glass transition and crystallization temperatures were studied by using TGA-DTA technique. Optical properties of Nd3+-doped telluride glasses were investigated between 298 and 700 K. Basing on the obtained values of J-O parameter values (x 10(-20) cm(2): Omega(2)=4.49 +/- 0.84, Omega(4)=5.03 +/- 0.61, Omega(6)=4.31 +/- 0.73), the radiative transition probabilities (A(T)), radiative lifetimes (tau(R)), fluorescence branching ratios (beta) and emission cross-sections (sigma(em)) were calculated for the F-4(3/2)-I-4(J/2) (where J=9, 11 and 13) transitions of Nd3+ ions. The tau(R) value of the F-4(3/2) level amount to 164 mu s and is slightly higher than the measured decay time of 162 mu s. With the increasing of Nd2O3 concentration from 0.5 to 7.0 mol% the experimental lifetime of the fluorescent level decreases from 162 to 5.6 mu s. The estimated quantum efficiency amount to 100%, based on a comparison of tau(R) and the experimental decay time of a slightly doped Nd3+ telluride glass. An analysis of the non-radiative decay was based on the cross-relaxation mechanisms. The F-4(3/2)-> I-4(9/2) and F-4(5/2)-> I-4(9/2) transitions were analyzed with respect to the fluorescence intensity ratio (FIR) and were found to be temperature dependent Infrared-to-visible up-conversion emissions with a maximum at 603.0 and 635.3 nm were observed at high temperatures using the 804 nm excitation and are due to the (4)G(5/2 ->)(4)I(9/2) and (4)G(5/2)-I-4(11/2) transitions of Nd3+ ions, respectively. The near quadratic dependence of fluorescence on excitation laser power confirms that two photons contribute to up-conversion of the orange emissions. The temperature-stimulated up-conversion excitation processes have been analyzed in detail. The optical results indicate that the investigated glasses. are potentially applicable as a 1063 nm laser host as well as an optical sensor for temperature measurements. (C) 2013 Elsevier Ltd. All rights reserved.