4.5 Article

Mid-infrared absorption cross-sections and temperature dependence of CFC-113

期刊

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jqsrt.2011.01.023

关键词

Chlorofluorocarbon; CFC-113; Freon 113; Cross-section; Mid-infrared; FTIR; Gas phase; Temperature dependence; Band strength

资金

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Canadian Space Agency (CSA)
  3. St. Francis Xavier University
  4. COMDEV
  5. Bomem
  6. Environment Canada

向作者/读者索取更多资源

The temperature dependence of the infrared absorption cross-sections of CFC-113 (1,1,2-trichlorotrifluoroethane) in a pure vapor phase has been recorded in the 600-1250 cm(-1) region using Fourier transform spectroscopy. Spectra at 0.05 cm(-1) resolution have been used to derive the integrated band strengths of the five main absorption bands over a range of temperatures from 223 to 283 K. Our results show good agreement with previously published data. The new cross-sections will allow more accurate retrieval of atmospheric CFC-113 concentrations using infrared spectroscopic techniques. (C) 2011 Elsevier Ltd. All rights reserved.

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