期刊
JOURNAL OF POWER SOURCES
卷 261, 期 -, 页码 238-244出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2014.03.057
关键词
Mesopore; Nitrogen-rich carbon; Electrocatalyst; Oxygen reduction reaction
资金
- National Natural Science Foundation of China [21163018, 21363022, 51362027]
Melamine-derived N-doped mesoporous carbon (MNMC) is synthesized by the pyrolysis of lysine and melamineunder at nitrogen atmosphere using ferric chloride as a dopant and SiO2 nanoparticles as hard templates to form mesoporous architecture. The N content in the bulk of carbon materials is as high as 113% and ca. 40.6% of N is in the form of pyridinic-N. The surface area of MNMC is ca. 650 m(2) g(-1) with a pore size distribution in the range of 2.2-34.5 nm. Compared to commercial Pt/C (20 wt%), MNMC exhibits much better electrocatalytic activity, better durability, and higher methanol tolerance for oxygen reduction reaction (ORR) in alkaline medium. Particularly, the onset ORR potential and half-wave ORR potential of MNMC are 1.059 and 0.871 V vs. RHE respectively, which are higher than those of commercial Pt/C. (c) 2014 Elsevier B.V. All rights reserved.
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