One-step hydrothermal method synthesis of core shell LiNi0.5Mn1.5O4 spinel cathodes for Li-ion batteries

Spherical LiNi0.5Mn1.5O4 material with a core-shell structure is synthesized by a urea-assisted hydrothermal method followed by heat treatment with LiOH at high temperature. After the process of hydrothermal treatment, the carbonate precursor with a concentration gradient is produced, in a single spherical particle, the content of Ni in the surface is higher than that in the center while Mn has a reversal trend. LiNi0.5Mn1.5O4 synthesized through the hydrothermal route has a great improvement in cycling stability at elevated temperature and rate capability. The capacity retention can maintain at 95% after 30 cycles at 55 degrees C. Furthermore, it can deliver a discharge capacity of 118 mAh g(-1) at a high rate of 10 C at room temperature. Such excellent electrochemical properties of LiNi0.5Mn1.5O4 can be ascribed to its unique core shell structure and nano-size particle. (C) 2014 Elsevier B.V. All rights reserved.