Nitrogen-doped carbon coated TiO2 nanocomposites as anode material to improve cycle life for lithium-ion batteries

Anatase TiO2 has attracted much attention as a safe anode material for lithium-ion battery applications, due to its low electronic conductivity and severe aggregation during Li+ insertion/extraction processes, the practical application of the anatase TiO2 is still hindered by poor long-term cycling stability. In order to improve the cycling performance of lithium-ion batteries, a uniform thin nitrogen-doped carbon layer with a thickness of 3-6 nm is successfully coated on the surface of the anatase TiO2 nanoparticles by using polydopamine as carbon precursor. Compared with the pristine TiO2 electrode, the carbon coated TiO2 nanocomposites electrodes show very good capacity retention and cycling performance. (C) 2013 Elsevier B.V. All rights reserved.