Investigation on gas generation of Li4Ti5O12/LiNi1/3Co1/3Mn1/3O2 cells at elevated temperature

The possible reasons and key factors on gas generation of Li4Ti5O12 (LTO) cells are investigated by the accelerating measurement baking at 80 degrees C for 120 h. It is found that the chemically catalytic reaction related to moisture makes a minor contribution to cell swelling. Our LTO-based 383450 cells (similar to 10 mL) before pre-charge (i.e. formation) only produce similar to 1.5 mL gas during baking test and CO2, instead of H-2, is the dominant species in EC/DMC electrolyte. By contrast, the swelling ratio of the charged LTO cells, which are re-sealed after formation, is kept at similar to 97% regardless of states of charge. This severe decomposition of carbonates at elevated temperature should be dominated by the anode potential, rather than catalysis of LTO, since graphite/NMC cells show a similar swelling behavior at over-discharge state, where graphite anode shares the same potential as LTO. On the other hand, the electrolyte stability is also dependent on the type of solvent. Among the investigated systems, the mixture of PC + DMC (1:1) exhibits the best behavior to suppress the cell swelling. The swelling ratio diminishes from similar to 100% of other electrolytes to 50%. This improvement probably roots in the high quality of protective films formed during solvents' decomposition. (C) 2013 Elsevier B.V. All rights reserved.