期刊
JOURNAL OF POWER SOURCES
卷 223, 期 -, 页码 341-348出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2012.09.062
关键词
SOFC; SOEC; Hydrogen electrode; Perovskite; Titanate; Exsolution
A new La0.5Sr0.5Ti0.75Ni0.25O3 (LSTN25) titanate was proposed as a hydrogen electrode for Solid Oxide Cells (SOCs) with electrochemical performance given by Ni nanoparticles exsoluted at the surface of a conducting oxide. As only in-situ reduction at 800 degrees C has been proposed in literature to perform Ni exsolution, the reduction at higher temperature of the LSTN25 compound was also considered in this work. The high-temperature treatment led to the precipitation of Ni nanoparticles evidenced by TEM observation and to an improved electrical conductivity that may be due to the formation of a sufficiently high concentration of Ti3+. Electrochemical study of symmetrical cells tested in H-2/H2O (97/3) showed a promising performance, with a polarization resistance of 0.55 Omega cm(2) at 800 degrees C and 0.46 Omega cm(2) after a thermal treatment in air that simulates the air electrode sintering. (C) 2012 Elsevier B.V. All rights reserved.
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