期刊
JOURNAL OF POWER SOURCES
卷 244, 期 -, 页码 328-335出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2013.01.028
关键词
Lithium-oxygen battery; Cathode; Manganese oxides; Metal decoration; Oxygen reduction; Oxygen evolution
资金
- Energy Efficiency & Resources of the Korea Institute of Energy Technology Evaluation and Planning [20112020100110]
- Korea government Ministry of Knowledge Economy
- Korea Evaluation Institute of Industrial Technology (KEIT) [20112020100110] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Rechargeable lithium-oxygen batteries have attracted considerable attention due to their high energy density. The critical challenges that limit the practical use of this technology include sluggish kinetics of the electrochemical oxygen reactions on the cathode during discharging and charging. Here, urchin-like alpha-MnO2 materials decorated with Au and Pd nanoparticles are developed for use as a cathode catalyst for rechargeable Li-O-2 batteries with hybrid electrolytes. Au and Pd particles as large as 3-8 nm are uniformly dispersed on the vertically aligned nanorods of alpha-MnO2. The Au/alpha-MnO2 and Pd/alpha-MnO2 catalysts show excellent bi-functional activity for both oxygen reduction and evolution. A rechargeable Li-O-2 battery with a hybrid electrolyte is constructed using the nanostructured composite catalysts. Charging and discharging experiments of the batteries indicate that the metal-decorated, urchin-like alpha-MnO2 can be used as an efficient bi-functional catalyst for rechargeable hybrid Li-O-2 batteries. (C) 2013 Elsevier B.V. All rights reserved.
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